Welcome Tony and we are sorry to hear about your wife's very unnerving experience. While there has been some overheating on a very small percentage of C7's, most of that has been in either tracking the car, or I know of a few folks stuck in stop-n-go when it was over 100 degrees. Doubt that at this time of the year, even if she was stuck for hours in stop-in-go, your temps have been any where near 100 degrees, let alone even the high 80's.
As one example, we were stuck in our '15 Z06 in horrible stop-n-go for an hour in 90 degree weather and while the temp rose to 235 , not higher.
Clearly something happened. My only idea, highly improbable, is that she had a plastic bag stuck in her radiator, but that is so improbable that it first got stuck then also worked its way back out of the grille. Hopefully someone else on the forum has a better idea of what could have happened.
Perhaps you did not find some ideas in this thread being useful, most specifcally a stuck thermostat??? That could explain a "one and done."
Welcome to StingRay Forums and we hope someone can give you some help, for I too would be concerned if that happened to my wife, i.e., might it happen again.